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Calculating π with Avogadro's Number

2021-03-10

[public] 346K views, 25.1K likes, 197 dislikes audio only

channel thumbStand-up Maths
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Check out Steve Mould's Pythagorean Siphon video: /youtube/video/Cg8KQfaT9xY

Every Pi Day I calculate the digits of π somehow. This year I counted the number of molecules in a disc as a 'real accurate' way to measure its surface area. You can see all the previous videos here: /youtube/video/CKl1B8y4qXw

Yes, you can buy the sheets of paper I wrote on in this video. I've signed them and all money goes to WaterAid UK. https://www.ebay.co.uk/usr/standupmaths

Here is the calculation (keeping mL and cm units throughout).

Our 7 drops were 0.1 mL of solution which is 0.00005 concentration.

Oleic acid is 282.47 g/mol and 0.895 g/mL.

Using Avogadro's number of 6.02214 × 10^23 that is 9.54 × 10^15 molecules of oleic acid.

That is a volume of 5.24081 × 10^-22 mL per molecule.

Which is a length of 8.06243 × 10^-8 cm and area of 6.50028 × 10^-15 cm^2.

Total area of 62.016 cm^2.

The disc of molecules had a radius of 4.000 cm and so that gives us π = 3.876 (I lost 0.001 because I was rounding as I went).

CORRECTIONS:

- No, I didn’t publish early by accident! I try to put π-Day videos out a bit early so teachers have time to use in lessons before/on π Day.

- I’m hearing reports that oleic acid is not an oil, the carboxylate end makes it a surfactant (first mentioned Ian Roberts). I blame any and all chemistry mistakes on Steve.

- Let me know if you spot any other mistakes!

Thanks to my Patreons who are vital in keeping the videos coming. Steve has a very expensive rider.

https://www.patreon.com/standupmaths

As always: thanks to Jane Street who support my channel. They're amazing.

https://www.janestreet.com/

Filming by Matt Parker and Steve Mould

Editing by Alex Genn-Bash

Music by Howard Carter

Design by Simon Wright and Adam Robinson

MATT PARKER: Stand-up Mathematician

Website: http://standupmaths.com/

US book: https://www.penguinrandomhouse.com/books/610964/humble-pi-by-matt-parker/

UK book: https://mathsgear.co.uk/collections/books/products/humble-pi-signed-paperback


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Stand-up Maths I do mathematics and stand-up. Sometimes simultaneously. Occasionally while being filmed. (It's quite the Venn diagram.) Principle channel supporter: Jane Street https://www.janestreet.com/ http://standupmaths.com http://twitter.com/standupmaths
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